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Updated: Jun 21, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Definir la estructura del catalizador activo y las vías de reacción desde la dinámica molecular ab initio y operando

Roger Rousseau1, Gregory K Schenter, John L Fulton

  • 1Fundamental & Computer Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, USA. roger.rousseau@pnl.gov

Journal of the American Chemical Society
|July 10, 2009
PubMed
Resumen

Este estudio revela una estructura dinámica de catalizador de racimo de Rh4 crucial para la deshidrogenación del dimetilaminoborane (DMAB). La especie fluxional identificada es compatible con los datos de XAFS, proponiendo un nuevo mecanismo catalítico.

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