Video Experimental Relacionado

Updated: Jun 21, 2026

One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates
06:00

One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates

Published on: January 15, 2018

Triflados anoméricos ecuatoriales de los ésteres del ácido mannurónico.

Marthe T C Walvoort1, Gerrit Lodder, Jaroslaw Mazurek

  • 1Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands.

Journal of the American Chemical Society
|August 12, 2009
PubMed
Resumen

Los triflados de ácido manuronico forman un inesperado intermediario triflado ecuatorial, estabilizado por grupos carboxilatos. Esta conformación explica la alta selectividad beta observada en las reacciones de glicosilación que involucran a los mannuronatos.

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