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Reacción de nitroaldol asimétrico catalítico anti-selectivo a través de un catalizador heterogéneo heterobimetálico

Tatsuya Nitabaru1, Akihiro Nojiri, Makoto Kobayashi

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|September 10, 2009
PubMed
Resumen

Un nuevo catalizador heterobimetálico promueve una reacción anti-selectiva asimétrica con nitroaldol. Este catalizador Nd/Na, aislado como precipitado, logra una alta estereoselectividad para el acoplamiento de nitroalcanos y aldehídos.

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