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Updated: Jun 20, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
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Química McMurry en TiO(2)(110): Acoplamiento reductivo C=C de benzaldehído impulsado por intersticiales de titanio

Lauren Benz1, Jan Haubrich, Ryan G Quiller

  • 1Department of Chemistry and Chemical Biology and School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|September 26, 2009
PubMed
Resumen

Los intersticiales de titanio del subsuelo en el dióxido de titanio reducido impulsan el acoplamiento selectivo del benzaldehído al stilbeno. Esta actividad catalítica, sostenida durante muchos ciclos, pone de relieve el papel crucial de los defectos a granel en la catálisis de óxidos.

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