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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Estructura y reactividad de los complejos de rutenio alquilideno quelatados con alquina

Kung-Pern Wang1, Sang Young Yun, Daesung Lee

  • 1Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061, USA.

Journal of the American Chemical Society
|October 6, 2009
PubMed
Resumen

Los investigadores sintetizaron un complejo de rutenio quelato con alquina estable utilizando metástasis secuencial de cierre de anillo de enyne y un desplazamiento metalotrópico. Este avance supera los desafíos en el aislamiento de complejos de rutenio alquilideno unidos al alquino.

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