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Catálisis a través de sustituciones homolíticas con enlaces C-O y Ti-O: adiciones oxidativas y eliminaciones

Andreas Gansäuer1, André Fleckhaus, Manuel Alejandre Lafont

  • 1Kekule-Institut für Organische Chemie und Biochemie der Universität Bonn, Gerhard Domagk Str. 1, 53121 Bonn, Germany. andreas.gansaeuer@uni-bonn.de

Journal of the American Chemical Society
|November 19, 2009
PubMed
Resumen

Los investigadores desarrollaron una reacción catalítica eficiente para la apertura de epóxidos y la formación de tetrahidrofuranos utilizando catalizadores de titanoceno. El rendimiento del catalizador se ajustó alterando las propiedades electrónicas, ofreciendo nuevas vías para el diseño de la reacción de transferencia de electrones.

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