Ciclización reductora asimétrica catalizada por el rodio de los 5-alquinas ligados al heteroatomo con acetaldehídos

Rie Tanaka1, Keiichi Noguchi, Ken Tanaka

  • 1Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.

Resumen

Un nuevo catalizador de rodio ((I) con H ((8) -BINAP permite la ciclización reductora asimétrica. Este proceso crea eficientemente valiosos compuestos quirales a partir de precursores simples con una alta enantioselectividad.

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