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Updated: Jun 16, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

Regioselectividad controlada por ligandos en reacciones de acoplamiento cruzado catalizadas por paladio

Franziska Schoenebeck1, K N Houk

  • 1Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA.

Journal of the American Chemical Society
|February 4, 2010
PubMed
Resumen

Un estudio computacional revela regioselectividad en el acoplamiento cruzado catalizado por paladio. Las interacciones Palladium-HOMO ArO-LUMO gobiernan la inserción de C-O, mientras que la inserción de C-Cl depende de la menor energía de distorsión del estado de transición de C-Cl.

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