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Updated: Jun 16, 2026

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Amida de plata quiral catalizada por enantioselectiva [3 + 2] cicloadición de alfa-aminofosfonatos con las olefinas

Yasuhiro Yamashita1, Xun-Xiang Guo, Ryuta Takashita

  • 1Department of Chemistry, School of Science, The University of Tokyo, and the HFRE Division, ERATO, Japan Science Technology Agency, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|February 19, 2010
PubMed
Resumen

Los investigadores desarrollaron las primeras cicloadiciones catalíticas asimétricas [3 + 2] utilizando bases Schiff de alfa-aminofosfonatos y olefinas. Este nuevo método produce análogos fosfónicos de prolina con alta selectividad utilizando catalizadores de plata quiral.

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