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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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Hidrogenación homogénea de CO: la activación de dihidrógeno implica un frustrado par de Lewis en lugar de un complejo

Alexander J M Miller1, Jay A Labinger, John E Bercaw

  • 1Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|February 25, 2010
PubMed
Resumen

Los investigadores descubrieron condiciones libres de metales para la reducción de CO utilizando un par frustrado de Lewis (FLP). Este sistema de base de fosfazeno y borano, activado por el dihidrógeno, permite las transferencias de hidruro y la formación de enlaces carbono-carbono.

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