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Catálisis enzimática de la ciclización de Nazarov por encapsulación supramolecular

Courtney J Hastings1, Michael D Pluth, Robert G Bergman

  • 1Department of Chemistry, University of California, Berkeley, California 94720-1460, USA.

Journal of the American Chemical Society
|May 7, 2010
PubMed
Resumen

Un nuevo conjunto tetraédrico K(12) Ga(4) L(6) cataliza eficientemente la ciclización de Nazarov bajo condiciones acuosas suaves. Este catalizador supramolecular acelera la reacción más de un millón de veces, imitando la eficiencia enzimática.

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