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Updated: Jun 13, 2026

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
12:07

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

Las adiciones de ciclo Diels-Alder catalizadas por nanopartículas de plata son cicloadiciones de 2'-hidroxicalcones

Huan Cong1, Clinton F Becker, Sean J Elliott

  • 1Department of Chemistry and Center for Chemical Methodology and Library Development, Boston University, Boston, Massachusetts 02215, USA.

Journal of the American Chemical Society
|May 7, 2010
PubMed
Resumen

Las nanopartículas de plata soportadas por sílice catalizan las reacciones de Diels-Alder para sintetizar productos naturales complejos como la panduratina A. Estos catalizadores reciclables ofrecen un alto rendimiento y rotación, avanzando las aplicaciones de nanopartículas en la síntesis química.

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Conformation
The simplest example of a diene is 1,3-butadiene, an acyclic conjugated π system. At room temperature, the molecule exists as a mixture of s-cis and s-trans conformers by virtue of rotation around the carbon–carbon single bond. Although the s-trans isomer is more stable, the...