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Updated: Jun 12, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Adición reversible de alcinos al complejo de galio de los ligandos de diamida quelante

Igor L Fedushkin1, Alexander S Nikipelov, Konstantin A Lyssenko

  • 1G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina str 49, 603950 Nizhny Novgorod, Russian Federation. igorfed@iomc.ras.ru

Journal of the American Chemical Society
|May 22, 2010
PubMed
Resumen

Las alcinas se agregan reversiblemente a un complejo de galio, formando nuevos enlaces carbono-carbono y carbono-galo. La temperatura de eliminación del alquino depende del adducto específico, con algunos eliminando por debajo de 100°C y otros cerca de 200°C.

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