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Preparation of Authigenic Pyrite from Methane-bearing Sediments for In Situ Sulfur Isotope Analysis Using SIMS
Published on: August 31, 2017
Explicando la estructura del registro de isótopos de azufre independientes de la masa del Arqueo
Itay Halevy1, David T Johnston, Daniel P Schrag
1Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA 02138, USA. itay.halevy@gmail.com
Resumen
Los antiguos registros de isótopos de azufre revelan la Tierra temprana.
Área de la Ciencia:
- La geoquímica es la geoquímica.
- Paleoclimatología Paleoclimatología
- Biogeoquímica La biogeoquímica es la bioquímica.
Sus antecedentes:
- Los isótopos de azufre en los sedimentos arqueos ofrecen información sobre las condiciones ambientales pasadas.
- La variabilidad y la asimetría a largo plazo en la fraccionamiento de isótopos de azufre permanecen sin explicación.
Objetivo del estudio:
- Investigar los factores que influyen en la preservación del azufre independiente de la masa en los sedimentos arqueos.
- Comprender las implicaciones para el ciclo de azufre de la Tierra primitiva y la actividad biológica.
Principales métodos:
- Utilizó un modelo biogeoquímico integrado del ciclo del azufre del Arcaico.
- Analizó la influencia de los mecanismos extraatmosféricos en los registros de isótopos de azufre.
Principales resultados:
- La preservación del azufre independiente de la masa sugiere un metabolismo limitado del azufre antes de hace 2.500 millones de años.
- La asimetría en el registro indica que la reducción de sulfato bacteriano no fue significativa durante este período.
- La variabilidad en el estado de oxidación de los volátiles volcánicos de azufre moldea el registro isotópico a gran escala.
Conclusiones:
- Los factores extraatmosféricos, incluyendo la biología y la formación de la corteza, controlan la preservación de isótopos de azufre.
- El ciclo de azufre de la Tierra primitiva era significativamente diferente, con una influencia microbiana limitada.
- La actividad volcánica jugó un papel clave en el establecimiento de los patrones de isótopos de azufre observados.
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