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Estrategia hipervalente lambda3-bromano para la oxidación de Baeyer-Villiger: transformación selectiva de aldehídos

Masahito Ochiai1, Akira Yoshimura, Kazunori Miyamoto

  • 1Graduate School of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph.tokushima-u.ac.jp

Journal of the American Chemical Society
|June 24, 2010
PubMed
Resumen

Una nueva estrategia de oxidación de Baeyer-Villiger (BVO) utiliza el hipervalente aril-lambda-bromano para convertir selectivamente los aldehídos en ésteres. Este método moderno supera las limitaciones del BVO clásico, logrando una alta selectividad para los aldehídos alifáticos y aromáticos.

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