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La construcción enantioselectiva de las espiroindoleninas por las reacciones de alquilación aliloide ir catalizada

Qing-Feng Wu1, Hu He, Wen-Bo Liu

  • 1State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.

Journal of the American Chemical Society
|August 4, 2010
PubMed
Resumen

Una nueva reacción catalizada por iridio permite la síntesis de derivados de espiroindolenina enriquecidos con enantio a partir de indoles. Este método logra altos rendimientos y una excelente estereoselectividad utilizando un ligando único de fosforamidita.

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