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Updated: Jun 10, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
10:12

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols

Published on: April 4, 2014

El acoplamiento cruzado alilo-alilo enantioselectivo catalizado por Pd cataliza el acoplamiento cruzado alilo-alilo

Ping Zhang1, Laura A Brozek, James P Morken

  • 1Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, USA.

Journal of the American Chemical Society
|August 5, 2010
PubMed
Resumen

Este estudio detalla una reacción de acoplamiento cruzado catalizada por paladio entre carbonatos alílicos y alilboronatos. El ángulo de mordedura del ligando controla la regioselectividad, favoreciendo los productos ramificados, y los ligandos quirales permiten la síntesis enantioselectiva de productos de sustitución alélica.

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