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Catalizador controlado formal [4 + 3] cicloadición aplicada a la síntesis total de (+) -barekoxido y (-) -barekol

Yajing Lian1, Laura C Miller, Stephen Born

  • 1Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, USA.

Journal of the American Chemical Society
|August 14, 2010
PubMed
Resumen

Este estudio introduce un nuevo tándem ciclopropanación / reordenamiento Cope para las cicloadiciones enantiodivergentes utilizando un catalizador de dirhodium. El método sintetiza eficientemente moléculas complejas como el barekoxido y el barekol.

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