Un complejo N-heterocíclico carbeno-disileno y su reactividad hacia ZnCl2

Torahiko Yamaguchi1, Akira Sekiguchi, Matthias Driess

  • 1Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.

PubMed
Resumen

Los investigadores sintetizaron un complejo de disilina con un carbeno N-heterocíclico (NHC). La complejación con cloruro de zinc indujo un cambio geométrico en el doble enlace silicio-silicio de trans a cis.

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