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Benzilación asimétrica catalizada por el paladio de 3-arilo oxindoles

Barry M Trost1, Lara C Czabaniuk

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA. bmtrost@stanford.edu

Journal of the American Chemical Society
|October 22, 2010
PubMed
Resumen

Los investigadores desarrollaron un nuevo método catalizado por el paladio para la alquilación bencílica asimétrica. Esta nueva reacción crea eficientemente centros de carbono cuaternarios utilizando 3-arilo oxindoles y carbonatos bencílicos, logrando altos rendimientos y enantioselectividad.

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