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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Cerrando la brecha entre la activación electroquímica y la organometálica: reducción de cloruro de bencilo en cátodos

Yi-Fan Huang1, De-Yin Wu, An Wang

  • 1State Key Laboratory of Physical Chemistry of Solid Surfaces and College of Chemistry and Chemical Engineering, Xiamen University, 361005 Xiamen, China.

Journal of the American Chemical Society
|November 13, 2010
PubMed
Resumen

Los cátodos de plata electrocatalizan de manera única la reducción del cloruro de bencilo al alterar el mecanismo de reacción a través de la adsorción de cloruro de bencilo. Esta interacción superficial produce distintos intermedios, a diferencia de los electrodos inertes, que muestran la excepcional actividad catalítica de la plata.

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