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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Síntesis de polímeros ROMP cis, sindiotácticos que contienen enantiómeros alternados

Margaret M Flook1, Victor W L Ng, Richard R Schrock

  • 1Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|January 27, 2011
PubMed
Resumen

La polimerización por metástasis de apertura de anillo de un derivado del norboreneno produce un polímero cis, sindiotáctico y alternante. Esto ocurre a través de una inversión intermedia de todos los cis y el centro del metal, creando polímeros con enantiómeros alternados.

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