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Updated: Jun 3, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

El control de la selectividad del sitio en reacciones de acoplamiento cruzado oxidativo catalizadas por Pd

Thomas W Lyons1, Kami L Hull, Melanie S Sanford

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|March 9, 2011
PubMed
Resumen

Este estudio revela cómo los promotores de quinona y los ligandos carboxilados controlan la selectividad del sitio en las reacciones de acoplamiento oxidativo catalizadas por el paladio. La sustitución de ligandos puede revertir la selectividad, ofreciendo un nuevo control sintético para la funcionalización del areno.

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