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Las trienaminas en la organocatálisis asimétrica: las reacciones Diels-Alder y en tándem

Zhi-Jun Jia1, Hao Jiang, Jun-Long Li

  • 1Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, and State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, 610041, China.

Journal of the American Chemical Society
|March 17, 2011
PubMed
Resumen

La organocatálisis permite un nuevo modo de activación utilizando aminas secundarias y polienales para formar intermediarios de trienamina. Estos intermediarios facilitan las reacciones de Diels-Alder, dando lugar a estructuras moleculares complejas con alto estereocontrol.

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