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Boroles de escalera fundidos con tiofeno con alta antiaromaticidad

Azusa Iida1, Shigehiro Yamaguchi

  • 1Department of Chemistry, Graduate School of Science, Nagoya University and JST-CREST, Furo, Chikusa, Nagoya 464-8602, Japan.

Journal of the American Chemical Society
|April 21, 2011
PubMed
Resumen

Los investigadores sintetizaron nuevos boroles fusionados con tiofeno, encontrando que su estructura única aumenta inesperadamente la antiaromaticidad. Estos sistemas π conjugados muestran propiedades ópticas y electrónicas distintas, desafiando las teorías existentes sobre los sistemas de anillos fusionados.

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