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Updated: May 31, 2026

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

Conocimientos mecánicos sobre los dicarboxilatos de zinc heterogéneos y consideraciones teóricas para la

Stephan Klaus1, Maximilian W Lehenmeier, Eberhardt Herdtweck

  • 1WACKER-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85747 Garching bei München, Germany.

Journal of the American Chemical Society
|July 13, 2011
PubMed
Resumen

Los dicarboxilatos de zinc heterogéneos catalizan la copolimerización del epoxido y el CO2. Este estudio explica las diferencias y limitaciones de la actividad al revelar un mecanismo bimetálico y distancias óptimas zinc-zinc para mejorar el diseño del catalizador.

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