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Updated: May 30, 2026

Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts
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Metal-free Synthesis of Ynones from Acyl Chlorides and Potassium Alkynyltrifluoroborate Salts

Published on: February 24, 2015

Ampliación del alcance del sustrato y mejora de la reactividad de las reacciones de acoplamiento cruzado de formación

Cam-Van T Vo1, T Andrew Mitchell, Jeffrey W Bode

  • 1Laboratorium für Organische Chemie, Department of Chemistry and Applied Biosciences, ETH-Zürich, Switzerland.

Journal of the American Chemical Society
|July 23, 2011
PubMed
Resumen

Un nuevo grupo de salida de hidroxamato permite una síntesis suave y eficiente de dialquilo éteres a través del acoplamiento cruzado de acetalos y organotrifluoroboratos. Este método ofrece mejores rendimientos y regioselectividad para varios sustratos, incluidos los difíciles ariltrifluoroboratos deficientes en electrones.

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