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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Reacciones de metátesis de olefinas Z-Selectivas promovidas por los complejos de tungsteno oxoalquilideno

Dmitry V Peryshkov1, Richard R Schrock, Michael K Takase

  • 1Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|November 24, 2011
PubMed
Resumen

Un nuevo catalizador de tungsteno facilita el acoplamiento de olefinas Z-selectivas, logrando altos rendimientos y estereoselectividad. La activación con compuestos de boro mejora la actividad catalítica para la formación de productos termodinámicos.

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