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Updated: May 24, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

A Ru(I) metalúrgico que cataliza el acoplamiento de nitreno a los azoarenos de las arilazidas

Ayumi Takaoka1, Marc-Etienne Moret, Jonas C Peters

  • 1California Institute of Technology, Division of Chemistry and Chemical Engineering, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|March 3, 2012
PubMed
Resumen

Los metalorrádicos de rutenio catalizan el acoplamiento N-N de azidas de arilo para formar azoarenos. El mecanismo de reacción implica el nitreno de arilo libre, no el acoplamiento bimolecular de especies de imidas metálicas.

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