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Fácil activación de los enlaces H-H y Si-H por los boranos

Georgii I Nikonov1, Sergei F Vyboishchikov, Oleg Sherbrooke

  • 1Chemistry Department, Brock University, St. Catharines, Ontario, Canada. gnikonov@brocku.ca

Journal of the American Chemical Society
|March 8, 2012
PubMed
Resumen

El precatalizador de borano B ((C ((6) F ((5)) ((3)) facilita el intercambio de H/D en silanos mediante la conversión a HB ((C ((6) F ((5)) ((2), que activa los enlaces H-H y Si-H a través de la metátesis de enlaces σ.

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