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El catalizador bifuncional promueve bromolactonizaciones altamente enantioselectivas para generar enlaces

Daniel H Paull1, Chao Fang, James R Donald

  • 1Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712, USA.

Journal of the American Chemical Society
|June 26, 2012
PubMed
Resumen

Un nuevo catalizador derivado de BINOL permite bromolactonizaciones altamente enantioselectivas de ácidos insaturados, incluidos los sustituidos por alquilo. Este avance logra la primera desimetrización catalítica de un ácido dienoico prociral.

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