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Fe ((III) / NaBH4-mediada por la hidrofluoración de radicales libres de alquenos no activados

Timothy J Barker1, Dale L Boger

  • 1Department of Chemistry and Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.

Journal of the American Chemical Society
|August 7, 2012
PubMed
Resumen

Una nueva reacción catalizada por hierro permite una hidrofluoración de radicales libres suave y eficiente de alquenos utilizando Selectfluor. Este método ofrece la adición exclusiva de Markovnikov en condiciones accesibles, superando las limitaciones de los enfoques tradicionales.

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