Video Experimental Relacionado

Updated: May 19, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
07:20

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

Published on: May 28, 2014

Control estructural del cruce intersistémico 1A2u-3A2u en los complejos diplatino ((II,II)

Alec C Durrell1, Gretchen E Keller, Yan-Choi Lam

  • 1Beckman Institute, California Institute of Technology, Pasadena, California 91125, USA.

Journal of the American Chemical Society
|August 8, 2012
PubMed
Resumen

El nuevo complejo per-difluoroboro-tetráquico-pirofosfito-diplatinato-II, Pt-pop-BF2), exhibe una velocidad de desintegración radiativa significativamente más rápida y un cruce intersistémico (ISC) más lento en comparación con su complejo Pt-pop. Esta mejora se debe a la reducción del acoplamiento de espín-órbita y al acceso limitado al disolvente.

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