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Mecanismos por los cuales los alcinos reaccionan con CpCr(CO) 3H. Aplicación para la ciclización radical

Deven P Estes1, Jack R Norton, Steffen Jockusch

  • 1Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA.

Journal of the American Chemical Society
|August 21, 2012
PubMed
Resumen

Este estudio investiga la reacción de CpCr ((CO) ((3) H con alquinos activados, revelando mecanismos distintos como la transferencia de átomos de hidrógeno (HAT) y la transferencia de electrones individuales (SET) en las reacciones de hidrogenación y ciclización.

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