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Resorcina con conmutación redox[4]areno cavitandos: agarres moleculares que se pueden cambiar por resorcina[4]areno:

Igor Pochorovski1, Marc-Olivier Ebert, Jean-Paul Gisselbrecht

  • 1Laboratorium für Organische Chemie, ETH Zürich, Hönggerberg, HCI, 8093 Zürich, Switzerland.

Journal of the American Chemical Society
|August 22, 2012
PubMed
Resumen

Las nuevas cavitandas basadas en diquinona cambian entre los estados abierto y cerrado a través del control redox, lo que permite la unión y liberación del huésped. Este interruptor molecular se basa en el enlace de hidrógeno intramolecular redox dependiente para la estabilidad.

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