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Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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6,6-Dicyanopentafulvenes: estructura electrónica y regioselectividad en las reacciones de [2 + 2]

Aaron D Finke1, Oliver Dumele, Michal Zalibera

  • 1Laboratory of Organic Chemistry, ETH Zurich, Hönggerberg, HCI, CH-8093 Zurich, Switzerland.

Journal of the American Chemical Society
|October 10, 2012
PubMed
Resumen

Estudiamos las 6,6-dicianopentafulvenas (DCF) que aceptan electrones y sus aniones radicales utilizando resonancia paramagnética electrónica (EPR). Los sustituyentes de sililalquinilo mostraron una deslocalización significativa de electrones, a diferencia de los sustituyentes de fenilo, que afectan la reactividad.

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