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El anti-Markovnikov asimétrico dirigido por el rodio regioselectivo boraciclopentanulado

Momar Toure1, Olivier Chuzel, Jean-Luc Parrain

  • 1Aix Marseille Université, CNRS, ISM2 UMR 7313, case 532, 13397, Marseille cedex 20, France.

Journal of the American Chemical Society
|October 20, 2012
PubMed
Resumen

Los investigadores desarrollaron un nuevo método utilizando carbenoboranos N-heterocíclicos activados por rodio (NHC-boranos) para la hidroboración intramolecular. Este avance supera las limitaciones de reactividad anteriores, permitiendo una síntesis eficiente de boranos cíclicos quirales.

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