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Updated: May 17, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
12:19

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization

Published on: November 29, 2018

Síntesis de sistemas de anillos policíclicos puentes a través de cascadas de carbenos que terminan en la inserción de

Santa Jansone-Popova1, Jeremy A May

  • 1Department of Chemistry, University of Houston, 136 Fleming Building, Houston, Texas 77204-5003, USA.

Journal of the American Chemical Society
|October 23, 2012
PubMed
Resumen

Este estudio introduce una nueva reacción en cascada de carbenos para sintetizar moléculas complejas bicíclicas puenteadas a partir de diazoesters de alquinyl fácilmente disponibles. El proceso ofrece estereoquímica controlada y diversas funcionalidades, expandiendo las capacidades de la química sintética.

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