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Spin Saturation Transfer Difference NMR (SSTD NMR): A New Tool to Obtain Kinetic Parameters of Chemical Exchange Processes
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Dinámica indirecta en una reacción de sustitución altamente exoérgica

Jochen Mikosch1, Jiaxu Zhang, Sebastian Trippel

  • 1National Research Council of Canada, Ottawa, Ontario K1A 0R6, Canada.

Journal of the American Chemical Society
|January 18, 2013
PubMed
Resumen

La reacción del anión fluoruro (F-) con el yoduro de metilo (CH3I) muestra una dinámica única, con una porción significativa que ocurre indirectamente a través de un complejo enlazado con hidrógeno, incluso a altas energías. Esto contrasta con otras reacciones de aniones halógenos, revelando mecanismos de reacción complejos.

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