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Adición de iones hidroxilo a la timina oxidada por un electrón: interconversión unimolecular de C5 a C6 adyuctos OH

Amitava Adhikary1, Anil Kumar, Alicia N Heizer

  • 1Department of Chemistry, Oakland University, Rochester, Michigan 48309, USA.

Journal of the American Chemical Society
|February 1, 2013
PubMed
Resumen

Este estudio investiga la adición de radicales hidroxilo a la timidina oxidada y los nucleótidos en condiciones básicas. La adición de radicales hidroxilo a los radicales timina forma intermedios que se convierten en otros radicales, con formas desprotonadas que reaccionan más fácilmente.

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