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15N CPMG Relaxation Dispersion for the Investigation of Protein Conformational Dynamics on the µs-ms Timescale
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Mediciones directas de la reactividad dependiente del conformador del intermediario Criegee CH3CHOOO

Craig A Taatjes1, Oliver Welz, Arkke J Eskola

  • 1Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551-0969, USA. cataatj@sandia.gov

Science (New York, N.Y.)
|April 13, 2013
PubMed
Resumen

Los investigadores estudiaron la cinética del intermediario Criegee más grande, el hidroperoxido de metilo (CH3CHOO). Encontraron una reactividad distinta para los sin- y anti-conformes, siendo el anti-CH3CHOO más reactivo hacia el agua y el dióxido de azufre.

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