El acoplamiento de alilo-alqueno enantioselectivo catalizado por iridio

James Y Hamilton1, David Sarlah, Erick M Carreira

  • 1Eidgenössische Technische Hochschule Zürich , HCI H335, 8093 Zürich, Switzerland.

Resumen

Este estudio introduce una nueva reacción de acoplamiento cruzado catalizada por iridio para sintetizar dienos y trienos complejos a partir de alcoholes y olefinas. El método eficiente logra una alta selectividad y enantioselectividad, lo que permite la síntesis de fármacos.

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