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Updated: Apr 28, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Published on: July 28, 2018

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Monofluoración directa y catalítica de enlaces sp3 C-H: un mecanismo basado en radicales con selectividad iónica

Cody Ross Pitts1, Steven Bloom, Ryan Woltornist

  • 1Department of Chemistry, Johns Hopkins University , 3400 North Charles Street, Baltimore, Maryland 21218, United States.

Journal of the American Chemical Society
|June 20, 2014
PubMed
Resumen

El cobre ((I) y el Selectfluor permiten una leve fluoración de C-H a través de un sorprendente mecanismo de cadena radical, con el cobre iniciando el proceso. Este estudio detalla el mecanismo y explica la preferencia por la monofluoración.

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