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Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra.
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Werner Heisenberg considered the limits of how accurately one can measure properties of an electron or other microscopic particles. He determined that there is a fundamental limit to how accurately one can measure both a particle’s position and its momentum simultaneously. The more accurate the measurement of the momentum of a particle is known, the less accurate the position at that time is known and vice versa. This is what is now called the Heisenberg uncertainty principle. He...
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In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
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Ras-related nuclear protein or Ran is a small G protein that cycles between its GTP and GDP bound states. Ran specific regulators, a Ran GTPase Activating Protein or RanGAP present in the cytosol and a Ran guanine nucleotide exchange factor or RanGEF present inside the nucleus regulate GTP/GDP exchange. A high concentration of GTP inside the cells, in addition to this asymmetric distribution of  Ran-specific regulators, leads to a higher RanGTP concentration inside the nucleus. This...
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Scalable Quantum Integrated Circuits on Superconducting Two-Dimensional Electron Gas Platform
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El túnel Domino es un túnel de domino.

Peter R Schreiner1, J Philipp Wagner1, Hans Peter Reisenauer1

  • 1⊥Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany.

Journal of the American Chemical Society
|June 2, 2015
PubMed
Resumen
Este resumen es generado por máquina.

El túnel mecánico cuántico impulsa la isomerización secuencial en los rotadores de ácido oxálico a temperaturas criogénicas. Este mecanismo de túnel "domino", observado en experimentos de aislamiento de matriz, revela una cinética compleja incluso cerca del cero absoluto.

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Área de la Ciencia:

  • Química Física es la química física.
  • La mecánica cuántica es la mecánica cuántica.
  • La espectroscopia es una técnica de espectroscopia.

Sus antecedentes:

  • El ácido oxálico exhibe múltiples rotameros O-H con diferentes energías relativas.
  • Comprender las transformaciones moleculares a temperaturas criogénicas es crucial para varios campos científicos.

Objetivo del estudio:

  • Para investigar el fenómeno de túneles mecánicos cuánticos en los rotadores de ácido oxálico.
  • Para caracterizar la cascada de isomerización secuencial y su cinética bajo condiciones de aislamiento de matriz.

Principales métodos:

  • Los experimentos de aislamiento de matriz se llevaron a cabo cerca de 3 K.
  • Computaciones químicas cuánticas de última generación.
  • Espectroscopia infrarroja (IR) para monitorear la evolución temporal de los rotameros.
  • Desarrollo de un modelo matemático general para la cinética de la cascada de reacción.

Principales resultados:

  • Se observó una cascada de isomerización secuencial (1tTt → 1cTt → 1cTc) en los rotameros de ácido oxálico.
  • Se identificaron semividas que oscilan entre 30 y 360 horas, lo que indica un túnel a través de barreras de alta energía.
  • Reveló clases distintas de sitios de matriz rápida y lenta que influyen en las tasas de decaimiento.
  • Acuerdo demostrado entre las tasas de desintegración experimentales y las tasas teóricas de túneles.

Conclusiones:

  • El ácido oxálico exhibe un nuevo fenómeno de túneles mecánicos cuánticos secuenciales.
  • Se trata de una de las
  • El domino es un domino.
  • El mecanismo de túneles gobierna estas transformaciones.
  • El modelo matemático desarrollado describe con precisión la cinética compleja en distintos sitios de la matriz.