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Updated: Apr 9, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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Acceso modular a los azocanos sustituidos a través de una estrategia de fragmentación-adición-ciclo catalizada por el

Megan H Shaw1, Rosemary A Croft1, William G Whittingham2

  • 1†School of Chemistry, University of Bristol, Bristol, BS8 1TS, United Kingdom.

Journal of the American Chemical Society
|June 20, 2015
PubMed
Resumen

Una nueva reacción de fragmentación por cicloadición catalizada por rodio proporciona una ruta concisa a los azocanos sustituidos. Este método utiliza N-ciclopropilacrilamidas y demuestra la naturaleza reversible de la inserción de alqueno en rhodacyclopentanones.

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