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(4+1) vs (4+2): Acoplamiento catalítico intramolecular entre las ciclobutanonas y los alenos trisubstituidos a través

Xuan Zhou1, Guangbin Dong1

  • 1Department of Chemistry, University of Texas at Austin , Austin, Texas 78712, United States.

Journal of the American Chemical Society
|October 7, 2015
PubMed
Resumen

Una nueva reacción catalizada por rodio crea moléculas complejas [4.2.1]-bicíclicas a partir de ciclobutanonas y alenos simples. Este método construye eficientemente dos centros de carbono cuaternarios con alta enantioselectividad, que ofrecen vías sintéticas versátiles.

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