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Updated: Mar 28, 2026

A Direct, Regioselective and Atom-Economical Synthesis of 3-Aroyl-N-hydroxy-5-nitroindoles by Cycloaddition of 4-Nitronitrosobenzene with Alkynones
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Mecanismo de la formación de indoles catalizados por Rh2: el catalizador no controla la selectividad del producto

Jason G Harrison1, Osvaldo Gutierrez1, Navendu Jana2

  • 1Department of Chemistry, University of California-Davis , 1 Shields Avenue, Davis, California 95616, United States.

Journal of the American Chemical Society
|January 1, 2016
PubMed
Resumen

Los estudios computacionales exploraron la síntesis de indol promovida por Rh a partir de vinilo / azidoarenos. Un mecanismo propuesto muestra que el catalizador Rh facilita la generación de nitrógeno pero no participa en el paso de ciclización.

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