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Angle of Twist: Problem Solving01:13

Angle of Twist: Problem Solving

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An electric motor applies a torque of 700 N·m to an aluminum shaft, triggering a stable rotation. Two pulleys, B and C, are subjected to torques of 300 N·m and 400 N·m, respectively. The modulus of rigidity is provided as 25 GPa. With the knowledge of the length and diameter of each segment, the twist angle between the two pulleys can be computed. First, a section cut is made between pulleys B and C, and the cut cross-section is analyzed using a free-body diagram. Given that the torque...
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Rotational Motion about a Fixed Axis01:26

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A rigid body's rotation around a fixed axis makes every point within it trace a circular path around a specific line or point. The term given to this type of spinning is defined by the angular position, symbolized by the angle θ. This angle is gauged from a static reference line to the revolving object. From this angular position, any variation is referred to as angular displacement, denoted by dθ. The extent of this displacement can be calculated in degrees, radians, or...
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Chair Conformation of Cyclohexane02:02

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The chair conformation is the most stable form of cyclohexane due to the absence of angle and torsional strain. The absence of angle strain is a result of cyclohexane’s bond angle being very close to the ideal tetrahedral bond angle of 109.5° in its chair conformer. Similarly, the torsional strain is also absent owing to the perfectly staggered arrangement of bonds.
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
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Thin-Walled Hollow Shafts01:15

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In analyzing a thin-walled hollow shaft subjected to torsional loading, a segment with width dx is isolated for examination. Despite its equilibrium state, this segment faces torsional shearing forces at its ends. These forces are quantitatively described by the product of the longitudinal shearing stress on the segment's minor surface and the area of this surface, leading to the concept of shear flow. This shear flow is consistent throughout the structure, indicating a uniform distribution of...
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Pivot Bearings01:23

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In mechanical systems, bearings are crucial in facilitating relative motion between two components while minimizing friction and wear. They help distribute various loads (radial, axial or a combination of both loads) across machinery parts, ensuring smooth and efficient operation.
A pivot bearing is a specialized type of bearing designed to support axial loads on a rotating shaft. The bearing surface, or the pivot, is positioned at the end of a shaft to support the axial thrust. The pivot may...
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Torque01:10

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Torque is an important quantity for describing the dynamics of a rotating rigid body. We see the application of torque in many ways in the world, such as when pressing the accelerator in a car, which causes the engine to apply additional torque on the drivetrain. Here, we define torque and provide a framework to create an equation to calculate torque for a rigid body with fixed-axis rotation.
Torque can be considered as the rotational counterpart to force. Since forces change the translational...
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Design and Implementation of a Bespoke Robotic Manipulator for Extra-corporeal Ultrasound
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Rotaxanos con tres hilos [4]

Jonathan J Danon1, David A Leigh1,2, Paul R McGonigal2

  • 1School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

Journal of the American Chemical Society
|August 30, 2016
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores sintetizaron rotaxanos complejos [4] con tres ejes enhebrados a través de un solo anillo utilizando la síntesis de plantilla metálica. Los macrociclos más grandes produjeron rotaxanos más complejos, demostrando el control de la plantilla en el ensamblaje molecular.

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Área de la Ciencia:

  • Química supramolecular
  • Síntesis orgánica

Sus antecedentes:

  • Los rotaxanos son moléculas mecánicamente entrelazadas con aplicaciones potenciales en nanotecnología.
  • La síntesis dirigida por plantillas es una estrategia clave para construir arquitecturas moleculares complejas.

Objetivo del estudio:

  • Síntesis y caracterización de nuevos [4]rotaxanos con múltiples ejes enroscados en un solo anillo macrocíclico.
  • Investigar la influencia del tamaño del macrociclo en la formación de rotaxano.

Principales métodos:

  • Sintez de plantillas metálicas activas mediante el uso de homoacoplamientos catalizables de níquel sp{3) -sp{3).
  • Preparación de "medios hilos" de bromuro de alquilo y macrociclos de 2,2':6',2'-terpiridil.
  • Caracterización de productos mediante espectroscopia de resonancia magnética nuclear (RMN) y espectrometría de masas.

Principales resultados:

  • Síntesis exitosa de rotaxanos triplamente roscados [4] con un rendimiento de hasta el 11% utilizando macrociclos de 37 y 38 miembros.
  • No se formaron productos de rotaxano con un macrociclo de 39 miembros en condiciones similares.
  • También se obtuvieron rotaxanos de doble rosca [3], lo que indica un posible deslizamiento del eje en macrociclos más grandes.

Conclusiones:

  • El tamaño del macrociclo es crítico para la síntesis exitosa de plantillas de rotaxanos altamente roscados [4].
  • Los resultados sugieren que los macrociclos más grandes pueden permitir el deslizamiento del eje después de la desmetalización, evitando el aislamiento de especies menos roscadas.