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Updated: Mar 9, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry

Published on: October 18, 2019

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¿Por qué la alquilación de la funcionalidad N-H dentro de los catalizadores de tipo Noyori bifuncionales M/NH conduce

Pavel A Dub1, Brian L Scott1, John C Gordon1

  • 1Chemistry Division, and ‡Materials and Physics Applications Division, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.

Journal of the American Chemical Society
|January 4, 2017
PubMed
Resumen

Los catalizadores bifuncionales moleculares de metal y NH son muy eficientes para la hidrogenación de carbonilo. La alquilación del enlace N-H, que anteriormente se creía crucial, en realidad dificulta la actividad al interrumpir los enlaces de hidrógeno estabilizadores.

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