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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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Heterocyclic aromatic compounds are cyclic compounds that are aromatic and have one or more heteroatoms—atoms other than carbon, in the ring. Depending upon the number of atoms present in the ring, they can be either five or six-membered. Examples of five-membered heterocyclic aromatic compounds include pyrrole, furan, thiophene, and imidazole. Pyrrole consists of one nitrogen atom having one lone pair of electrons. Furan and thiophene have one oxygen and one sulfur heteroatom,...
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In this lesson, we delve into the role of ring conformation and its stability, which determines the spatial arrangement and, consequently, the molecular symmetry and stereoisomerism of cyclic compounds. 1,2-Dimethylcyclohexane is used as a case study to evaluate the possible number of stereoisomers. Here, given the multiple (n = 2) chiral centers, there are 2n = 4 possible configurations that lack a plane of symmetry, as the ring skeleton exists in a non-planar chair conformation. In addition,...
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Septins are protein filaments forming the cytoskeleton along with the microtubules, microfilaments, intermediate filaments, and other accessory proteins. In 1971 while studying the cell division cycle in mutant Saccharomyces cerevisiae Harwell et al. first identified the septin-related genes playing a crucial role in yeast cytokinesis. Fluorescence microscopy revealed that these proteins localize at the budding neck as rings. These ring-like proteins were then named Septins by John Pringle, and...
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The inscribed polygon method is consistent with Hückel’s 4n + 2 rule and helps to learn whether the given cyclic compound is aromatic or not. The compound is stable and aromatic if every bonding molecular orbital (MO) is completely filled with a pair of electrons. However, if the non-bonding or antibonding orbitals are filled with electrons, the compound is unstable and not aromatic. Consider the Frost circle diagrams for cycloalkenes containing 4 to 8 carbons.
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Electrocyclic reactions, cycloadditions, and sigmatropic rearrangements are concerted pericyclic reactions that proceed via a cyclic transition state. These reactions are stereospecific and regioselective. The stereochemistry of the products depends on the symmetry characteristics of the interacting orbitals and the reaction conditions. Accordingly, pericyclic reactions are classified as either symmetry-allowed or symmetry-forbidden. Woodward and Hoffmann presented the selection criteria for...
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Una molécula de engranaje de tripticeno sextuple dispuesta en círculo

Hitoshi Ube1, Ryo Yamada1, Jun-Ichi Ishida1

  • 1Department of Chemistry, Graduate School of Science, The University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|October 25, 2017
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores sintetizaron un nuevo sistema de engranajes moleculares con seis engranajes de triptíceno. La fijación de un complejo de rutenio restringido los engranajes

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Área de la Ciencia:

  • Mecánica molecular y química supramolecular.
  • Síntesis orgánica y catálisis.
  • Ciencias de los materiales.

Sus antecedentes:

  • Las máquinas moleculares basadas en triptíceno son cruciales para la ingeniería a nanoescala.
  • Diseñar arquitecturas moleculares complejas con movimiento controlado es un desafío.

Objetivo del estudio:

  • Para sintetizar una nueva molécula de engranaje de tríptceno ordenado circularmente.
  • Para investigar el compromiso mecánico y el movimiento de estos engranajes moleculares.
  • Explorar el potencial para controlar el movimiento molecular a través del acoplamiento mecánico.

Principales métodos:

  • Síntesis a través de la trimización catalizada por cobalto de un precursor de triina.
  • Caracterización estructural mediante difracción de rayos X de un solo cristal.
  • Análisis dinámico del comportamiento a través de la espectroscopia de resonancia magnética nuclear (RMN).

Principales resultados:

  • Sintetizó con éxito hexakis ((10-dodeciloxi-9-triptícilo) etinilbenceno, una molécula con seis engranajes de triptíceno entrelazados.
  • Se ha confirmado la activación mecánica de los engranajes de triptíceno en estado sólido.
  • Movimiento molecular observado y caracterizado en solución utilizando RMN.
  • Movimiento restringido demostrado de todo el sistema de engranajes tras la fijación de un complejo de rutenio voluminoso (RuCp*) a un único engranaje.

Conclusiones:

  • La molécula sintetizada representa un sistema multigear funcional con potencial para el movimiento molecular controlado.
  • El compromiso mecánico es clave para regular el movimiento colectivo de los engranajes moleculares.
  • Este trabajo proporciona una base para el desarrollo de sistemas de transmisión molecular con capacidades de conmutación.